Selective Electron Transfer Reduction of Urea-Type Carbonyls
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چکیده
منابع مشابه
Proton-coupled electron transfer in the reduction of carbonyls using SmI2-H2O: implications for the reductive coupling of acyl-type ketyl radicals with SmI2-H2O.
Samarium diiodide-water (SmI2-H2O) reagents have emerged as some of the most practical systems enabling reduction and reductive cyclizations of ketyl radicals. Recently, this reaction manifold has been extended to acyl-type radicals generated from cyclic polar carboxylic acid derivatives. However, the relationship between the fundamental electron- and proton-transfer steps in the generation of ...
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.....................................................................................................53 Introduction ................................................................................................54 Materials and Methods ...............................................................................58 Results ........................................................................
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ژورنال
عنوان ژورنال: European Journal of Organic Chemistry
سال: 2018
ISSN: 1434-193X
DOI: 10.1002/ejoc.201800794